34 research outputs found
Nearly quantized conductance plateau of vortex zero mode in an iron-based superconductor
Majorana zero-modes (MZMs) are spatially-localized zero-energy fractional
quasiparticles with non-Abelian braiding statistics that hold a great promise
for topological quantum computing. Due to its particle-antiparticle
equivalence, an MZM exhibits robust resonant Andreev reflection and 2e2/h
quantized conductance at low temperature. By utilizing variable-tunnel-coupled
scanning tunneling spectroscopy, we study tunneling conductance of vortex bound
states on FeTe0.55Se0.45 superconductors. We report observations of conductance
plateaus as a function of tunnel coupling for zero-energy vortex bound states
with values close to or even reaching the 2e2/h quantum conductance. In
contrast, no such plateau behaviors were observed on either finite energy
Caroli-de Genne-Matricon bound states or in the continuum of electronic states
outside the superconducting gap. This unique behavior of the zero-mode
conductance reaching a plateau strongly supports the existence of MZMs in this
iron-based superconductor, which serves as a promising single-material platform
for Majorana braiding at a relatively high temperature
Molecular epidemiology and antimicrobial resistance patterns of carbapenem-resistant Acinetobacter baumannii isolates from patients admitted at ICUs of a teaching hospital in Zunyi, China
BackgroundCarbapenem-resistant Acinetobacter baumannii (CRAB) has emerged as a predominant strain of healthcare-associated infections worldwide, particularly in intensive care units (ICUs). Therefore, it is imperative to study the molecular epidemiology of CRAB in the ICUs using multiple molecular typing methods to lay the foundation for the development of infection prevention and control strategies. This study aimed to determine the antimicrobial susceptibility profile, the molecular epidemiology and conduct homology analysis on CRAB strains isolated from ICUs.MethodsThe sensitivity to various antimicrobials was determined using the minimum inhibitory concentration (MIC) method, Kirby-Bauer disk diffusion (KBDD), and E-test assays. Resistance genes were identified by polymerase chain reaction (PCR). Molecular typing was performed using multilocus sequence typing (MLST) and multiple-locus variable-number tandem repeat analysis (MLVA).ResultsAmong the 79 isolates collected, they exhibited high resistance to various antimicrobials but showed low resistance to levofloxacin, trimethoprim-sulfamethoxazole, and tetracyclines. Notably, all isolates of A. baumannii were identified as multidrug-resistant A. baumannii (MDR-AB). The blaOXA-51-like, adeJ, and adeG genes were all detected, while the detection rates of blaOXA-23-like (97.5%), adeB (93.67%), blaADC (93.67%), qacEΔ1-sul1 (84.81%) were higher; most of the Ambler class A and class B genes were not detected. MLST analysis on the 79 isolates identified five sequence types (STs), which belonged to group 3 clonal complexes 369. ST1145Ox was the most frequently observed ST with a count of 56 out of 79 isolates (70.89%). MLST analysis for non-sensitive tigecycline isolates, which were revealed ST1145Ox and ST1417Ox as well. By using the MLVA assay, the 79 isolates could be grouped into a total of 64 distinct MTs with eleven clusters identified in them. Minimum spanning tree analysis defined seven different MLVA complexes (MCs) labeled MC1 to MC6 along with twenty singletons. The locus MLVA-AB_2396 demonstrated the highest Simpson’s diversity index value at 0.829 among all loci tested in this study while also having one of the highest variety of tandem repeat species.ConclusionThe molecular diversity and clonal affinities within the genomes of the CRAB strains were clearly evident, with the identification of ST1144Ox, ST1658Ox, and ST1646Oxqaq representing novel findings
Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation.
Producing hydrogen by water electrolysis suffers from the kinetic barriers in the oxygen evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in OER, to manipulate the spin ordering of ferromagnetic OER catalysts (e.g., by magnetization) can reduce the kinetic barrier. However, most active OER catalysts are not ferromagnetic, which makes the spin manipulation challenging. In this work, we report a strategy with spin pinning effect to make the spins in paramagnetic oxyhydroxides more aligned for higher intrinsic OER activity. The spin pinning effect is established in oxideFM/oxyhydroxide interface which is realized by a controlled surface reconstruction of ferromagnetic oxides. Under spin pinning, simple magnetization further increases the spin alignment and thus the OER activity, which validates the spin effect in rate-limiting OER step. The spin polarization in OER highly relies on oxyl radicals (O∙) created by 1st dehydrogenation to reduce the barrier for subsequent O-O coupling
Superconductivity and orbital-selective nematic order in a new titanium-based kagome metal CsTi3Bi5
Fabrication of new types of superconductors with novel physical properties
has always been a major thread in the research of superconducting materials. An
example is the enormous interests generated by the cascade of correlated
topological quantum states in the newly discovered vanadium-based kagome
superconductors AV3Sb5 (A=K, Rb, and Cs) with a Z2 topological band structure.
Here we report the successful fabrication of single-crystals of titanium-based
kagome metal CsTi3Bi5 and the observation of superconductivity and electronic
nematicity. The onset of the superconducting transition temperature Tc is
around 4.8 K. In sharp contrast to the charge density wave superconductor
AV3Sb5, we find that the kagome superconductor CsTi3Bi5 preserves translation
symmetry, but breaks rotational symmetry and exhibits an electronic nematicity.
The angular-dependent magnetoresistivity shows a remarkable two-fold rotational
symmetry as the magnetic field rotates in the kagome plane. The scanning
tunneling microscopy and spectroscopic imaging detect rotational-symmetry
breaking C2 quasiparticle interference patterns (QPI) at low energies,
providing further microscopic evidence for electronic nematicity. Combined with
first-principle calculations, we find that the nematic QPI is orbital-selective
and dominated by the Ti dxz and dyz orbitals, possibly originating from the
intriguing orbital bond nematic order. Our findings in the new "135" material
CsTi3Bi5 provide new directions for exploring the multi-orbital correlation
effect and the role of orbital or bond order in the electron liquid crystal
phases evidenced by the symmetry breaking states in kagome superconductors
Selfassembled synthesis of SERS-active silver dendrites and photoluminescence properties of a thin porous silicon layer, Electrochem
Abstract Via electroless metal deposition, well-defined silver dendrites and thin porous silicon (por-Si) layers are simultaneously prepared in ammonia fluoride solution containing AgNO 3 at 50°C. A self-assembled localized microscopic electrochemical cell model and a diffusion-limited aggregation mode are used to explain the growth of silver dendrites. The formation of silver dendritic nanostructures derives from the continuous aggregation growth of small particles on a layer of silver nanoparticles or nanoclusters (Volmer-Weber layer). Thin and homogeneous nanostructure por-Si layers display visible light-emission properties at room temperature. The investigation of the surface-enhanced Raman scattering (SERS) reveals that the film of silver dendrites on por-Si is an excellent substrate with significant enhancement effect
Low-temperature controllable preparation of vertically standing graphene sheets on indium tin oxide glass and their field emission properties
© 2016 Elsevier B.V.Vertically standing graphene sheets (VSGs) were successfully grown on indium tin oxide (ITO) glass through plasma enhanced chemical vapor deposition system. The lateral size of the graphene sheets was evidently affected by the growth temperature. The VSGs with smaller sheet size were obtained at 600 °C than at 500 °C. The dependence of the field-emission behavior of VSGs grown on ITO glass (VSGs/ITO) on the sheet size was investigated. The VSGs/ITO films with smaller sheet size possessed a higher field-enhancement factor and a lower turn-on field, which was proposed to be attributed to more field-emission sites and better electrical conductivity.Link_to_subscribed_fulltex